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Analysis of ITO cleaning protocol on surface properties and polymer: Fullerene bulk heterojunction solar cell performance

Identifieur interne : 001148 ( Main/Repository ); précédent : 001147; suivant : 001149

Analysis of ITO cleaning protocol on surface properties and polymer: Fullerene bulk heterojunction solar cell performance

Auteurs : RBID : Pascal:13-0238870

Descripteurs français

Pascal (Inist)
- Addition étain, Propriété surface, Polymère, Hétérojonction, Cellule solaire, Evaluation performance, Cellule solaire organique, Couche ITO, Mouillabilité, Analyse surface, Analyse énergétique, Transport charge, Facteur limitant, Rayonnement UV, Coût, Spectre photoélectron RX, Oxyde d'indium, Fullerènes, Ozone, ITO.
Wicri :
- concept : Polymère, Ozone.

English descriptors

KwdEn :
- Charge transport, Costs, Energy analysis, Fullerenes, Heterojunction, ITO layers, Indium oxide, Limiting factor, Organic solar cells, Ozone, Performance evaluation, Polymer, Solar cell, Surface analysis, Surface properties, Tin addition, Ultraviolet radiation, Wettability, X-ray photoelectron spectra.

Abstract

In the traditional organic solar cell architecture, indium tin oxide (ITO) serves as the transparent electrode and substrate for solution-cast device layers. Hydrophobic contaminants are known to modify ITO wettability and other properties, making selection of an effective cleaning scheme essential. In this work, we demonstrate that certain solvent-based routines provide essentially equivalent surface properties as coupled solvent+UV-ozone protocols reported in literature. Surface energy analysis further reveals that solvent selection can effectively tune ITO charge transport. Fabricated devices showed comparable performance, indicating that interfacial resistances are not limiting factors in the model OSC system and that UV-ozone exposure could be eliminated to reduce commercialization costs.

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Pascal:13-0238870

Le document en format XML

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<author><name sortKey="Clark, Michael D" uniqKey="Clark M">Michael D. Clark</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB</s1>
<s2>OH 45433</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>États-Unis</country>
<placeName><region type="state">Ohio</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Leever, Benjamin J" uniqKey="Leever B">Benjamin J. Leever</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB</s1>
<s2>OH 45433</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>États-Unis</country>
<placeName><region type="state">Ohio</region>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">13-0238870</idno>
<date when="2013">2013</date>
<idno type="stanalyst">PASCAL 13-0238870 INIST</idno>
<idno type="RBID">Pascal:13-0238870</idno>
<idno type="wicri:Area/Main/Corpus">000A64</idno>
<idno type="wicri:Area/Main/Repository">001148</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0927-0248</idno>
<title level="j" type="abbreviated">Sol. energy mater. sol. cells</title>
<title level="j" type="main">Solar energy materials and solar cells</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Charge transport</term>
<term>Costs</term>
<term>Energy analysis</term>
<term>Fullerenes</term>
<term>Heterojunction</term>
<term>ITO layers</term>
<term>Indium oxide</term>
<term>Limiting factor</term>
<term>Organic solar cells</term>
<term>Ozone</term>
<term>Performance evaluation</term>
<term>Polymer</term>
<term>Solar cell</term>
<term>Surface analysis</term>
<term>Surface properties</term>
<term>Tin addition</term>
<term>Ultraviolet radiation</term>
<term>Wettability</term>
<term>X-ray photoelectron spectra</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Addition étain</term>
<term>Propriété surface</term>
<term>Polymère</term>
<term>Hétérojonction</term>
<term>Cellule solaire</term>
<term>Evaluation performance</term>
<term>Cellule solaire organique</term>
<term>Couche ITO</term>
<term>Mouillabilité</term>
<term>Analyse surface</term>
<term>Analyse énergétique</term>
<term>Transport charge</term>
<term>Facteur limitant</term>
<term>Rayonnement UV</term>
<term>Coût</term>
<term>Spectre photoélectron RX</term>
<term>Oxyde d'indium</term>
<term>Fullerènes</term>
<term>Ozone</term>
<term>ITO</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Polymère</term>
<term>Ozone</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">In the traditional organic solar cell architecture, indium tin oxide (ITO) serves as the transparent electrode and substrate for solution-cast device layers. Hydrophobic contaminants are known to modify ITO wettability and other properties, making selection of an effective cleaning scheme essential. In this work, we demonstrate that certain solvent-based routines provide essentially equivalent surface properties as coupled solvent+UV-ozone protocols reported in literature. Surface energy analysis further reveals that solvent selection can effectively tune ITO charge transport. Fabricated devices showed comparable performance, indicating that interfacial resistances are not limiting factors in the model OSC system and that UV-ozone exposure could be eliminated to reduce commercialization costs.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0927-0248</s0>
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<fA03 i2="1"><s0>Sol. energy mater. sol. cells</s0>
</fA03>
<fA05><s2>116</s2>
</fA05>
<fA08 i1="01" i2="1" l="ENG"><s1>Analysis of ITO cleaning protocol on surface properties and polymer: Fullerene bulk heterojunction solar cell performance</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>CLARK (Michael D.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>LEEVER (Benjamin J.)</s1>
</fA11>
<fA14 i1="01"><s1>Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB</s1>
<s2>OH 45433</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<fA20><s1>270-274</s1>
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<fA21><s1>2013</s1>
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<fA23 i1="01"><s0>ENG</s0>
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<fA43 i1="01"><s1>INIST</s1>
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<fA44><s0>0000</s0>
<s1>© 2013 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>30 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>13-0238870</s0>
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<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Solar energy materials and solar cells</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>In the traditional organic solar cell architecture, indium tin oxide (ITO) serves as the transparent electrode and substrate for solution-cast device layers. Hydrophobic contaminants are known to modify ITO wettability and other properties, making selection of an effective cleaning scheme essential. In this work, we demonstrate that certain solvent-based routines provide essentially equivalent surface properties as coupled solvent+UV-ozone protocols reported in literature. Surface energy analysis further reveals that solvent selection can effectively tune ITO charge transport. Fabricated devices showed comparable performance, indicating that interfacial resistances are not limiting factors in the model OSC system and that UV-ozone exposure could be eliminated to reduce commercialization costs.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D06C02D1</s0>
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<fC02 i1="02" i2="X"><s0>001D05I03D</s0>
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<fC02 i1="03" i2="X"><s0>230</s0>
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<fC03 i1="01" i2="X" l="FRE"><s0>Addition étain</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Tin addition</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Adición estaño</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Propriété surface</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Surface properties</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Propiedad superficie</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Polymère</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Polymer</s0>
<s5>03</s5>
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<fC03 i1="03" i2="X" l="SPA"><s0>Polímero</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Hétérojonction</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Heterojunction</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Heterounión</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Cellule solaire</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Solar cell</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Célula solar</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Evaluation performance</s0>
<s5>06</s5>
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<fC03 i1="06" i2="X" l="ENG"><s0>Performance evaluation</s0>
<s5>06</s5>
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<fC03 i1="06" i2="X" l="SPA"><s0>Evaluación prestación</s0>
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<s5>07</s5>
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<s5>07</s5>
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<fC03 i1="08" i2="3" l="FRE"><s0>Couche ITO</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>ITO layers</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Mouillabilité</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Wettability</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Remojabilidad</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Analyse surface</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Surface analysis</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Análisis superficie</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Analyse énergétique</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Energy analysis</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Análisis energético</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Transport charge</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG"><s0>Charge transport</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Facteur limitant</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Limiting factor</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Factor limitante</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Rayonnement UV</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Ultraviolet radiation</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Radiación ultravioleta</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Coût</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Costs</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Coste</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>Spectre photoélectron RX</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG"><s0>X-ray photoelectron spectra</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Oxyde d'indium</s0>
<s5>22</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Indium oxide</s0>
<s5>22</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Indio óxido</s0>
<s5>22</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Fullerènes</s0>
<s5>23</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG"><s0>Fullerenes</s0>
<s5>23</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Ozone</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>24</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Ozone</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>24</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Ozono</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>24</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>ITO</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fN21><s1>224</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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Analysis of ITO cleaning protocol on surface properties and polymer: Fullerene bulk heterojunction solar cell performance

Analysis of ITO cleaning protocol on surface properties and polymer: Fullerene bulk heterojunction solar cell performance

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri